UCLA law student turned model Gabrielle Union made the jump again to acting via single-episode appearances on the hit series Moesha, Malibu Shores, and Saved By the Bell: The New Class in 1996. Movies followed, including the teen smashes She's All That (1999), 10 Things I Hate About You (1999), and H-E Double Hockey Sticks (1999). (OK, maybe that last one wasn't much of a smash.) After a lead role on the short-lived series City of Angels, Gabrielle returned to the silver screen in such films as Love & Basketball (2000), Bring It On (2000), and Bad Boys II (2003), certifying her place in Hollywood history as a bona fide star. Since then, she's had TV roles in Life (2009), Flashforward (2009), and Being Mary Jane (2013). As for a boner-inducing hottie, yes, she's got that covered, too. (Sadly, she's already married to Dwyane Wade.) The state of this Union will be very closely watched!