Sarah Lancaster in Chuck (2007-2012)

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One day electronics-store geek Chuck Bartowski (Zachary Levi) wakes up to discover that his brain is now standing in for a government super computer housing all the country’s secrets and he’s being recruited into life as a super spy. The downside? He can’t tell anyone he knows about his new career—oh, and there’s that whole fighting off assassins and terrorists thing. The upside? Chuck gets to pretend that super hot spy Yvonne Strahovski is his lady love. If Chuck isn’t up for the job, Mr Skin is!