Vinessa Shaw in 40 Days and 40 Nights (2002)
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Josh Hartnett has apocalyptic visions whenever he's about to close the deal with a lady love in 40 Days and 40 Nights (2002). Therefore, he does what any red-blooded American male (in a wacky movie plot) would do: he seeks religious counsel and pledges to give up all forms of sex for Lent. This leads to every hottie in San Francisco coming on to him and his meeting electrically exotic Shannyn Sossamon, the girl of his wet dreams.